- Jennifer Aniston Character (Annie Hughes (voice))
- Harry Connick Jr. Character (Dean McCoppin (voice))
- Vin Diesel Character (The Iron Giant (voice))
- Cloris Leachman Character (Mrs. Lynley Tensedge (voice))
- James Gammon Character (Foreman Marv Loach / Floyd Turbeaux (voice))
- Christopher McDonald Character (Kent Mansley (voice))
- John Mahoney Character (General Rogard (voice))
- Eli Marienthal Character (Hogarth Hughes (voice))
- M. Emmet Walsh Character (Earl Stutz (voice))
- Jack Angel Character (Additional Voices)
- Bob Bergen Character (Additional Voices)
- Mary Kay Bergman Character (Additional Voices)
- Michael Bird Character (Additional Voices)
- Devon Cole Borisoff Character (Additional Voices)
- Rodger Bumpass Character (Additional Voices)
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